Sulphur: Difference between revisions
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'''Sulphur''' (''aka'' '''sulfur''') is a [[Chemical elements|chemical element]], typically found as a yellowish crystalline [[Solid_(state_of_matter)|solid]] in its elemental form. It has the [[chemical symbol]] S, [[atomic number]] (number of [[protons]]) ''Z'' = 16, and a [[Atomic mass#Standard atomic weights of the elements|standard atomic weight]] of 32.065 g/mol. | |||
Sulphur is widely used in the manufacture of [[sulphuric acid]] (H<sub>2</sub>SO<sub>4</sub>} as well as various fertilisers. The vast majority of the 66,000,000 metric tons of sulphur produced worldwide in 2006 was by-product sulphur recovered from [[Petroleum refining processes|petroleum refining]] and [[Natural gas processing|natural gas processing plants]] by the [[Claus process]].<ref>[http://minerals.usgs.gov/minerals/pubs/commodity/sulphur/sulfumcs07.pdf Sulphur production report] by the [[United States Geological Survey]]</ref> | |||
==Characteristics== | ==Characteristics== | ||
At room temperature, sulphur is a soft, bright-yellow solid. Elemental sulphur has only a faint odour, similar to that of [[matches]]. | |||
At room temperature, | |||
Sulphur burns with a blue flame that emits [[sulphur dioxide]], notable for its peculiar suffocating odour due to dissolving in the mucosa to form dilute [[sulphurous acid]]. | |||
Sulphur itself is insoluble in water, but [[solubility|soluble]] in [[carbon disulfide]] and to a lesser extent in other non-polar organic solvents such as [[benzene]] and [[toluene]]. | |||
Common [[oxidation state]]s of | Common [[oxidation state]]s of sulphur include −2, +2, +4 and +6. Sulphur forms stable compounds with all elements except the [[noble gas]]es. Sulphur in the solid state ordinarily exists as cyclic crown-shaped S<sub>8</sub> [[molecule]]s. | ||
{{Image| | {{Image|Sulphur crystals.jpg|right|175px|Sulphur crystals}} | ||
The [[crystallography]] of | The [[crystallography]] of sulphur is complex. Depending on the specific conditions, the sulphur [[allotrope]]s form several distinct [[crystal structure]]s, with [[rhombic]] and [[monoclinic]] S<sub>8</sub> best known. | ||
A noteworthy property of | A noteworthy property of sulphur is that its [[viscosity]] in its molten state, unlike most other liquids, increases above temperatures of 200 °C due to the formation of [[polymer]]s. The molten sulphur assumes a dark red colour above this temperature. At higher temperatures, however, the viscosity is decreased as depolymerization occurs. | ||
[[Amorphous]] or "plastic" | [[Amorphous]] or "plastic" sulphur can be produced through the rapid cooling of molten sulphur. [[X-ray crystallography]] studies show that the amorphous form may have a [[helix|helical]] structure with eight atoms per turn. This form is [[Metastability in molecules|metastable]] at room temperature and gradually reverts back to crystalline form. This process happens within a matter of hours to days but can be rapidly catalysed. | ||
==References== | ==References== | ||
{{reflist}} | {{reflist}} | ||
Latest revision as of 09:21, 6 March 2024
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Sulphur (aka sulfur) is a chemical element, typically found as a yellowish crystalline solid in its elemental form. It has the chemical symbol S, atomic number (number of protons) Z = 16, and a standard atomic weight of 32.065 g/mol.
Sulphur is widely used in the manufacture of sulphuric acid (H2SO4} as well as various fertilisers. The vast majority of the 66,000,000 metric tons of sulphur produced worldwide in 2006 was by-product sulphur recovered from petroleum refining and natural gas processing plants by the Claus process.[1]
Characteristics
At room temperature, sulphur is a soft, bright-yellow solid. Elemental sulphur has only a faint odour, similar to that of matches.
Sulphur burns with a blue flame that emits sulphur dioxide, notable for its peculiar suffocating odour due to dissolving in the mucosa to form dilute sulphurous acid.
Sulphur itself is insoluble in water, but soluble in carbon disulfide and to a lesser extent in other non-polar organic solvents such as benzene and toluene.
Common oxidation states of sulphur include −2, +2, +4 and +6. Sulphur forms stable compounds with all elements except the noble gases. Sulphur in the solid state ordinarily exists as cyclic crown-shaped S8 molecules.
The crystallography of sulphur is complex. Depending on the specific conditions, the sulphur allotropes form several distinct crystal structures, with rhombic and monoclinic S8 best known.
A noteworthy property of sulphur is that its viscosity in its molten state, unlike most other liquids, increases above temperatures of 200 °C due to the formation of polymers. The molten sulphur assumes a dark red colour above this temperature. At higher temperatures, however, the viscosity is decreased as depolymerization occurs.
Amorphous or "plastic" sulphur can be produced through the rapid cooling of molten sulphur. X-ray crystallography studies show that the amorphous form may have a helical structure with eight atoms per turn. This form is metastable at room temperature and gradually reverts back to crystalline form. This process happens within a matter of hours to days but can be rapidly catalysed.