User:Milton Beychok/Sandbox: Difference between revisions

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<ref>{{cite web| url=http://oceanworld.tamu.edu/resources/oceanography-book/radiationbalance.htm| title=Earth's Radiation Balance and Oceanic Heat Fluxes| first=|last=}}</ref><ref>{{cite web| url=http://www-pcmdi.llnl.gov/projects/cmip/overview_ms/control_tseries.pdf
<ref>{{cite web| url=http://oceanworld.tamu.edu/resources/oceanography-book/radiationbalance.htm| title=Earth's Radiation Balance and Oceanic Heat Fluxes| first=|last=}}</ref><ref>{{cite web| url=http://www-pcmdi.llnl.gov/projects/cmip/overview_ms/control_tseries.pdf
| title=Coupled Model Intercomparison Project Control Run| first=|last=}}</ref>
| title=Coupled Model Intercomparison Project Control Run| first=|last=}}</ref>
== Composition ==
{{main|Atmospheric chemistry}}
Filtered air includes trace amounts of many of the [[chemical element]]s. Substantial amounts of argon, nitrogen, and oxygen are present as [[elementary gas]]es. Note the major [[greenhouse gas]]es: water vapor, carbon dioxide, methane, nitrous oxide, and ozone. Many additional elements from natural sources may be present in tiny amounts in an unfiltered air sample, including contributions from [[dust]], [[pollen]] and [[spores]], [[sea spray]], [[vulcanism]], and [[meteoroid]]s. Various industrial [[pollutant]]s are also now present in the air, such as [[chlorine]] (elementary or in compounds), [[fluorine]] (in compounds), elementary [[Mercury (element)|mercury]], and [[sulfur]] (in compounds such as [[sulfur dioxide]] [SO<sub>2</sub>]).
{| class="wikitable"
|+'''Composition of dry atmosphere, by volume'''<ref>Source for figures: Carbon dioxide, [http://nssdc.gsfc.nasa.gov/planetary/factsheet/earthfact.html NASA Earth Fact Sheet], (updated 2007.01). Methane, [[Intergovernmental Panel on Climate Change|IPCC]] [http://www.grida.no/climate/ipcc_tar/wg1/221.htm#tab61 TAR table 6.1], (updated to 1998). The NASA total was 17 ppmv over 100%, and CO<sub>2</sub> was increased here by 15 ppmv. To normalize, N<sub>2</sub> should be reduced by about 25 ppmv and O<sub>2</sub> by about 7 ppmv.</ref>
|colspan=2 style="font-size: 85%" |''ppmv: [[parts per million]] by volume''
|-
!align = "left" | Gas
!align = "left" |Volume
|-
| [[Nitrogen]] (N<sub>2</sub>) || 780,840 ppmv (78.084%)
|-
| [[Oxygen]] (O<sub>2</sub>) || 209,460 ppmv (20.946%)
|-
| [[Argon]] (Ar) || 9,340 ppmv (0.9340%)
|-
| [[Carbon dioxide]] (CO<sub>2</sub>) || 383 ppmv (0.0383%)
|-
| [[Neon]] (Ne) || 18.18 ppmv (0.001818%)
|-
| [[Helium]] (He) || 5.24 ppmv (0.000524%)
|-
| [[Methane]] (CH<sub>4</sub>) || 1.745 ppmv (0.0001745%)
|-
| [[Krypton]] (Kr) || 1.14 ppmv (0.000114%)
|-
| [[Hydrogen]] (H<sub>2</sub>) || 0.55 ppmv (0.000055%)
|-
| [[Nitrous oxide]] (N<sub>2</sub>O) || 0.3 ppmv (0.00003%)
|-
| [[Xenon]] (Xe) || 0.09 ppmv (9x10<sup>−6</sup>%)
|-
| [[Ozone]] (O<sub>3</sub>) || 0.0 to 0.07 ppmv (0%-7x10<sup>−6</sup>%)
|-
| [[Nitrogen dioxide]] (NO<sub>2</sub>) || 0.02 ppmv (2x10<sup>−6</sup>%)
|-
| [[Iodine]] (I) || 0.01 ppmv (1x10<sup>−6</sup>%)
|-
| [[Carbon monoxide]] (CO) || 0.1 ppmv
|-
| [[Ammonia]] (NH<sub>3</sub>) || trace
|-
| Colspan=2 |'''Not included in above dry atmosphere:'''
|-
| [[Water vapor]] (H<sub>2</sub>O) || ~0.40% over full atmosphere, typically 1%-4% at surface
|}

Revision as of 21:55, 14 August 2009

Atmospheric gases scatter blue light more than other wavelengths, giving the Earth a blue halo when seen from space

The Earth's atmosphere is a layer of gases surrounding the planet Earth that is retained by the Earth's gravity. It has a mass of about five quadrillion metric tons. Dry air contains roughly (by volume) 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.038% carbon dioxide, and trace amounts of other gases. Air also contains a variable amount of water vapor, on average around 1%. The atmosphere protects life on Earth by absorbing ultraviolet solar radiation, warming the surface through heat retention (greenhouse effect), and reducing temperature extremes between day and night.

There is no definite boundary between the atmosphere and outer space. It slowly becomes thinner and fades into space. An altitude of 120 km (74.56 mi) marks the boundary where atmospheric effects become noticeable during atmospheric reentry. The Kármán line, at 100 km (62.14 mi), is also frequently regarded as the boundary between atmosphere and outer space. Three quarters of the atmosphere's mass is within 11 km (Expression error: Missing operand for round. mi ft) of the surface.

Temperature and layers

Layers of the atmosphere (not to scale)

The temperature of the Earth's atmosphere varies with altitude; the mathematical relationship between temperature and altitude varies among five different atmospheric layers (ordered highest to lowest, the ionosphere is part of the thermosphere):

Exosphere
From 500 - (Expression error: Unrecognized word "km". 1000) up to 10000 km (Expression error: Missing operand for round. mi ft), contain free-moving particles that may migrate into and out of the magnetosphere or the solar wind.
Exobase
Also known as the 'critical level', it is the lower boundary of the exosphere.
Ionosphere
The part of the atmosphere that is ionized by solar radiation stretches from 50 to (Expression error: Unrecognized word "km". 1000) and typically overlaps both the exosphere and the thermosphere. It plays an important part in atmospheric electricity and forms the inner edge of the magnetosphere. Because of its charged particles, it has practical importance because it influences, for example, radio propagation on the Earth. It is responsible for auroras.
Thermopause
The boundary above the thermosphere, it varies in height from 500 - (Expression error: Unrecognized word "km". 1000).
Thermosphere
From 80 - (Expression error: Unrecognized word "km". 85) to over 640 km (Expression error: Missing operand for round. mi ft), temperature increasing with height. The temperature of this layer can rise to 1500 C (Expression error: Missing operand for round. {{{3}}}). The International Space Station orbits in this layer, between 320 and (Expression error: Unrecognized word "km". 380).
Mesopause
The temperature minimum at the boundary between the thermosphere and the mesosphere. It is the coldest place on Earth, with a temperature of -100 C (Expression error: Missing operand for round. F K).
Mesosphere
From the Greek word "μέσος" meaning middle. The mesosphere extends from about 50 km (Expression error: Missing operand for round. mi ft) to the range of 80 - (Expression error: Unrecognized word "km". 85). Temperature decreases with height, reaching -100 C (Expression error: Missing operand for round. F K) in the upper mesosphere. This is also where most meteors burn up when entering the atmosphere.
Stratopause
The boundary between the mesosphere and the stratosphere, typically 50 to (Expression error: Unrecognized word "km". 55). The pressure here is 1/1000th sea level.
Stratosphere
From the Latin word "stratus" meaning spreading out. The stratosphere extends from the troposphere's 7 - (Expression error: Unrecognized word "km". 17) range to about 51 km (Expression error: Missing operand for round. mi ft). Temperature increases with height. The stratosphere contains the ozone layer, the part of the Earth's atmosphere which contains relatively high concentrations of ozone. "Relatively high" means a few parts per million—much higher than the concentrations in the lower atmosphere but still small compared to the main components of the atmosphere. It is mainly located in the lower portion of the stratosphere from approximately 15 - (Expression error: Unrecognized word "km". 35) above Earth's surface, though the thickness varies seasonally and geographically.
Ozone Layer
Though part of the Stratosphere, the ozone layer is considered as a layer of the Earth's atmosphere in itself because its physical and chemical composition is far different from the Stratosphere. Ozone (O3) in the Earth's stratosphere is created by ultraviolet light striking oxygen molecules containing two oxygen atoms (O2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O2 to create O3. O3 is unstable (although, in the stratosphere, long-lived) and when ultraviolet light hits ozone it splits into a molecule of O2 and an atom of atomic oxygen, a continuing process called the ozone-oxygen cycle. This occurs in the ozone layer, the region from about 10 to (Expression error: Unrecognized word "km". 50) above Earth's surface. About 90% of the ozone in our atmosphere is contained in the stratosphere. Ozone concentrations are greatest between about 20 and (Expression error: Unrecognized word "km". 40), where they range from about 2 to 8 parts per million.
Tropopause
The boundary between the stratosphere and troposphere.
Troposphere
From the Greek word "τρέπω" meaning to turn or change. The troposphere is the lowest layer of the atmosphere; it begins at the surface and extends to between 7 km (22965.88 ft) at the poles and 17 km (55774.28 ft) at the equator, with some variation due to weather factors. The troposphere has a great deal of vertical mixing because of solar heating at the area. This heating makes air masses less dense so they rise. When an air mass rises, the pressure upon it decreases so it expands, doing work against the opposing pressure of the surrounding air. To do work is to expend energy, so the temperature of the air mass decreases. As the temperature decreases, water vapor in the air mass may condense or solidify, releasing latent heat that further uplifts the air mass. This process determines the maximum rate of decline of temperature with height, called the adiabatic lapse rate. The troposphere contains roughly 80% of the total mass of the atmosphere. Fifty percent of the total mass of the atmosphere is located in the lower 5.6 km (18372.7 ft) of the troposphere.

The average temperature of the atmosphere at the surface of Earth is 14 C (Expression error: Missing operand for round. F K)[1] or 15 C (Expression error: Missing operand for round. F K)[2], depending on the reference.[3] [4][5]

Composition

For more information, see: Atmospheric chemistry.


Filtered air includes trace amounts of many of the chemical elements. Substantial amounts of argon, nitrogen, and oxygen are present as elementary gases. Note the major greenhouse gases: water vapor, carbon dioxide, methane, nitrous oxide, and ozone. Many additional elements from natural sources may be present in tiny amounts in an unfiltered air sample, including contributions from dust, pollen and spores, sea spray, vulcanism, and meteoroids. Various industrial pollutants are also now present in the air, such as chlorine (elementary or in compounds), fluorine (in compounds), elementary mercury, and sulfur (in compounds such as sulfur dioxide [SO2]).

Composition of dry atmosphere, by volume[6]
ppmv: parts per million by volume
Gas Volume
Nitrogen (N2) 780,840 ppmv (78.084%)
Oxygen (O2) 209,460 ppmv (20.946%)
Argon (Ar) 9,340 ppmv (0.9340%)
Carbon dioxide (CO2) 383 ppmv (0.0383%)
Neon (Ne) 18.18 ppmv (0.001818%)
Helium (He) 5.24 ppmv (0.000524%)
Methane (CH4) 1.745 ppmv (0.0001745%)
Krypton (Kr) 1.14 ppmv (0.000114%)
Hydrogen (H2) 0.55 ppmv (0.000055%)
Nitrous oxide (N2O) 0.3 ppmv (0.00003%)
Xenon (Xe) 0.09 ppmv (9x10−6%)
Ozone (O3) 0.0 to 0.07 ppmv (0%-7x10−6%)
Nitrogen dioxide (NO2) 0.02 ppmv (2x10−6%)
Iodine (I) 0.01 ppmv (1x10−6%)
Carbon monoxide (CO) 0.1 ppmv
Ammonia (NH3) trace
Not included in above dry atmosphere:
Water vapor (H2O) ~0.40% over full atmosphere, typically 1%-4% at surface
  1. Earth's Atmosphere.
  2. NASA - Earth Fact Sheet
  3. Global Surface Temperature Anomalies.
  4. Earth's Radiation Balance and Oceanic Heat Fluxes.
  5. Coupled Model Intercomparison Project Control Run.
  6. Source for figures: Carbon dioxide, NASA Earth Fact Sheet, (updated 2007.01). Methane, IPCC TAR table 6.1, (updated to 1998). The NASA total was 17 ppmv over 100%, and CO2 was increased here by 15 ppmv. To normalize, N2 should be reduced by about 25 ppmv and O2 by about 7 ppmv.