Molar gas constant

From Citizendium
Revision as of 23:32, 1 April 2008 by imported>Milton Beychok (Added a section on relation between universal gas constant and the gas-specific constant)
Jump to navigation Jump to search
This article is a stub and thus not approved.
Main Article
Discussion
Related Articles  [?]
Bibliography  [?]
External Links  [?]
Citable Version  [?]
 
This editable Main Article is under development and subject to a disclaimer.

In chemistry and physics, the molar gas constant R is a physical constant with the value:[1]   8.314 472  J mol−1K−1.

The constant R is equal to the Boltzmann constant times Avogadro's constant: R = kBNA.

The constant arises in equations of state, most notably in the ideal gas law

where p is the pressure, Vm the molar volume, and T the absolute temperature of the ideal gas.

= Notation for the gas constant

The gas constant defined in this article is the universal gas constant, , that applies to any gas. There is also a gas-specific version of the gas constant, which can be denoted as . The gas-specific constant is defined as where is the molecular weight.

Unfortunately, many authors in the technical literature sometimes use as the gas-specific constant without denoting it as such or stating that it is the gas-specific constant. This can and does lead to confusion.


Reference

  1. Obtained on 16 December, 2007 from NIST