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Steam is the vapor (gaseous) phase of water (H2O). When the steam does not contain any liquid water, it is known as dry steam and it is completely colorless. However, when the steam contains tiny droplets of condensed liquid water, it appears to the eye as a white cloud (see the steam being vented from a geothermal power plant in the adjacent photograph).

What is very often referred to as smoke from cooling towers and other vents in industrial facilities is water vapor which has partially condensed and is mistaken to be white smoke.

Steam is manufactured in industrial processes by the boiling and vaporization of liquid water. It also occurs naturally by being vented from volcanoes, fumaroles, geysers and other geothermal sources.

Steam has a great many industrial and domestic uses. Probably the most important and by far the largest use of steam is in nuclear, fossil fuel and geothermal power plants .


Forms of steam

Saturated steam

Steam at equilibrium with liquid water is commonly referred to as saturated steam.[1]. It defines the boundary between wet steam and superheated steam on the temperature-enthalpy diagram.

Superheated steam

Superheated steam is steam at a temperature higher than its boiling point at a given pressure. For superheating to take place one of two things must occur. Either all of the liquid water must have evaporated or, in the case of steam generators (boilers), the saturated steam must be conveyed out of the steam drum before superheating can occur, as steam can not be superheated in the presence of liquid water.[2]

There are three stages of heating to convert liquid water to superheated steam. First the liquid water’s sensible (the heat that can be measured with a thermometer) heat is raised. Then latent heat (this heat does not raise the temperature of the fluid) is added. After all of the liquid is evaporated or the saturated steam is taken from the steam drum sensible heat is again added superheating the steam.

Uses

Electricity generation

In the U.S., more than 86% of electric power is produced using steam as the working fluid, nearly all by steam turbines. Condensation of steam to water often occurs at the low-pressure end of a steam turbine, since this maximizes the energy efficiency, but such wet-steam conditions have to be limited to avoid excessive turbine blade erosion.

Cogeneration

In electric generation, steam is typically condensed at the end of its expansion cycle, and returned to the boiler for re-use. However in cogeneration, steam is piped into buildings through a district heating system to provide heat energy after its use in the electric generation cycle. The world's biggest steam generation system is the New York City steam system which pumps steam into 100,000 buildings in Manhattan from seven cogeneration plants.[3]

Steam engines

A steam engine uses the expansion of steam in order to drive a piston or turbine to perform mechanical work. The ability to return condensed steam as water-liquid to the boiler at high pressure with relatively little expenditure of pumping power is important. Engineers use an idealised thermodynamic cycle, the Rankine cycle, to model the behavior of steam engines.

Heat transfer in industrial process facilities

Other uses

Sterilization
An autoclave, which uses steam under pressure, is used in microbiology laboratories and similar environments for sterilization.
Agricultural
In agriculture steam is used for soil sterilization to avoid the use of harmful chemical agents and increase soil health.
Domestic uses
Steam's capacity to transfer heat is also used in the home: for cooking vegetables, steam cleaning of fabric and carpets, and heating buildings. In each case, water is heated in a boiler, and the steam carries the energy to a target object. "Steam showers" are actually low-temperature mist-generators, and do not actually use steam.

Steam tables and diagrams

Steam tables are tables of thermodynamic data for water/steam. They are often used by engineers and scientists in design and operation of equipment where thermodynamic cycles involving steam are used. Additionally, thermodynamic phase diagrams for water/steam, such as a temperature-entropy diagram or a Mollier diagram shown in this article, may be useful.