Hydrogen-like atom

A hydrogen-like atom is an atom with one electron. Except for the hydrogen atom itself (which is neutral) these atoms carry positive charge e(Z-1), where Z is the atomic number of the atom. Because hydrogen-like atoms are two-particle systems with an interaction depending only on the distance between the two particles, their (non-relativistic) Schrödinger equation can be solved in analytic form. The solutions are one-electron functions and are referred to as hydrogen-like atomic orbitals. These orbitals differ from one another in one respect only: the nuclear charge eZ appears in the radial part of the wave function.

Quantum numbers

Hydrogen-like atomic orbitals are eigenfunctions of the square of the one-electron angular momentum vector operator l ≡ (l_x, l_y, l_z) and of l_z. The operator l² ≡ l_x² + l_y² + l_z² has eigenvalue $\hbar ^{2}l(l+1)$. The operator l_z has eigenvalue $\hbar m$.

The energies of the orbitals do not depend on the angular momentum quantum numbers l and m, but solely on the principal quantum number n. The degeneracy (maximum number of linearly independent eigenfunctions of same energy) of energy level n is equal to n². This is the dimension of the irreducible representations of the symmetry group of hydrogen-like atoms, which is SO(4).

A hydrogen-like atomic orbital is uniquely identified by the values of the principal quantum number n, the angular momentum quantum number l, and the magnetic quantum number m. They are integers and can have the following values:

$n=1,2,3,4,\dots ,$

$l=0,1,2,\dots ,n-1,$

$m=-l,-l+1,\ldots ,0,\ldots ,l-1,l,$

To this must be added the two-valued spin quantum number ms = ±½ in application of the exclusion principle. This principle restricts the allowed values of the four quantum numbers in electron configurations of more-electron atoms: it is forbidden that two electrons have the same four quantum numbers.

Completeness of hydrogen-like orbitals

In quantum chemical calculations hydrogen-like atomic orbitals cannot serve as an expansion basis, because they are not complete. The non-square-integrable continuum (E > 0) states must be included to obtain a complete set, i.e., to span all of one-electron Hilbert space.

Schrödinger equation

The atomic orbitals of hydrogen-like atoms are solutions of the time-independent Schrödinger equation in a potential given by Coulomb's law:

$V(r)=-{\frac {1}{4\pi \epsilon _{0}}}{\frac {Ze^{2}}{r}}$

where

• ε₀ is the permittivity of the vacuum,
• Z is the atomic number (charge of the nucleus in unit e),
• e is the elementary charge (charge of an electron),
• r is the distance of the electron from the nucleus.

After writing the wave function as a product of functions:

$\psi (r,\theta ,\phi )=R(r)Y_{lm}(\theta ,\phi )\,$

(in spherical coordinates), where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle Y_{lm}} are spherical harmonics, we arrive at the following Schrödinger equation:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left[ - \frac{\hbar^2}{2\mu} \left({1 \over r^2}{\partial \over \partial r}\left(r^2 {\partial R(r)\over \partial r}\right) + {l(l+1)R\over r^2} \right) + V(r)R(r) \right]= E R(r), }

where μ is, approximately, the mass of the electron. More accurately, it is the reduced mass of the system consisting of the electron and the nucleus. Because the electron mass is about 1836 smaller than the mass of the lightest nucleus (the proton), the value of μ is very close to the mass of the electron m_e for all hydrogenic atoms. In the remaining of the article we will often make the approximation μ = m_e. Since m_e will appear explicitly in the formulas it will be easy to correct for this approximation if necessary.

Wave function and energy

In addition to l and m, there arises a third integer n > 0 from the boundary conditions imposed on R(r). The final expression for the normalized wave function is:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \psi_{nlm} = R_{nl}(r)\, Y_{lm}(\theta,\phi)}

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle R_{nl} (r) = \sqrt {{\left ( \frac{2 Z}{n a_{\mu}} \right ) }^3\frac{(n-l-1)!}{2n[(n+l)!]} } e^{- Z r / {n a_{\mu}}} \left ( \frac{2 Z r}{n a_{\mu}} \right )^{l} L_{n-l-1}^{2l+1} \left ( \frac{2 Z r}{n a_{\mu}} \right ) }

where:

• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle L_{n-l-1}^{2l+1}} are the generalized Laguerre polynomials in the definition given here.
• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle a_{\mu} = {{4\pi\varepsilon_0\hbar^2}\over{\mu e^2}}}

Note that Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle a_{\mu}\,} is approximately equal to Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle a_0\,} (the Bohr radius). If the mass of the nucleus is infinite then Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mu = m_e\,} and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle a_\mu = a_0\,} .

• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle E_{n} = -\frac{\mu}{2} \left( \frac{e^2}{4 \pi \varepsilon_0 \hbar n}\right)^2 } . (Energy eigenvalues. As we pointed out above they depend only on n, not on l or m).

• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle Y_{lm} (\theta,\phi)\,} function is a spherical harmonic.

Solution

The kinetic energy operator in spherical polar coordinates is

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{\hat{p}^2}{2m_e} = -\frac{\hbar^2}{2m_e} \nabla^2 = - \frac{\hbar^2}{2m_e\,r^2}\left[ \frac{\partial}{\partial r}\Big(r^2 \frac{\partial}{\partial r}\Big) - \hat{l}^2 \right]. }

The spherical harmonics satisfy

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \hat{l}^2 Y_{lm}(\theta,\phi)\equiv \left\{ -\frac{1}{\sin^2\theta} \left[ \sin\theta\frac{\partial}{\partial\theta} \Big(\sin\theta\frac{\partial}{\partial\theta}\Big) +\frac{\partial^2}{\partial \phi^2}\right]\right\} Y_{lm}(\theta,\phi) = l(l+1)Y_{lm}(\theta,\phi)} .

Substituting this into the Schrödinger equation we get a one-dimensional eigenvalue equation,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left \{ - {\hbar^2 \over 2m_e r^2} {d\over dr}(r^2{d\over dr}) +{\hbar^2 l(l+1)\over 2m_e r^2}+V(r) \right \} R(r)=ER(r)}

Note that the first term in the kinetic energy can be rewritten

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T_r\equiv \frac{1}{r^2} \frac{d}{dr}r^2\frac{d}{dr} = \frac{1}{r}\frac{d^2}{dr^2}r} .

This follows because both sides of this equation can be shown by application of the product rule to be equal to a third form of this operator:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T_r = \frac{d^2}{dr^2}+\frac{2}{r}\frac{d}{dr}. }

If subsequently the substitution Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle u(r)\ \stackrel{\mathrm{def}}{=}\ rR(r)} is made into

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle -{\hbar^2 \over 2m_e} \frac{1}{r} {d^2 \over dr^2}r\,R(r) + \left(V(r) + {\hbar^2l(l+1) \over 2m_e r^2}\right)\, R(r) = E\, R(r), }

the radial equation becomes

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle -{\hbar^2 \over 2m_e} {d^2 u(r) \over dr^2} + V_{\mathrm{eff}}(r) u(r) = E u(r)}

which is precisely a Schrödinger equation for the function u(r) with an effective potential given by

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V_{\mathrm{eff}}(r) = V(r) + {\hbar^2l(l+1) \over 2m_e r^2},}

where the radial coordinate r ranges from 0 to Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \infty} . The correction to the potential V(r) is called the centrifugal barrier term.

In order to simplify the Schrödinger equation, we introduce the following constants that define the atomic unit of energy and length, respectively,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle E_\textrm{h} = m_e \left( \frac{e^2}{4 \pi \varepsilon_0 \hbar}\right)^2 \quad\hbox{and}\quad a_{0} = {{4\pi\varepsilon_0\hbar^2}\over{m_e e^2}}} .

Substitute Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle y = Zr/a_0\,} and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle W = E/(Z^2 E_\textrm{h})\,} into the radial Schrödinger equation given above. This gives an equation in which all natural constants are hidden,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left[ -\frac{1}{2} \frac{d^2}{dy^2} + \frac{1}{2} \frac{l(l+1)}{y^2} - \frac{1}{y}\right] u_l = W u_l . }

Two classes of solutions of this equation exist: (i) W is negative, the corresponding eigenfunctions are square integrable and the values of W are quantized (discrete spectrum). (ii) W is non-negative. Every real non-negative value of W is physically allowed (continuous spectrum), the corresponding eigenfunctions are non-square integrable. In the remaining part of this article only class (i) solutions will be considered. The wavefunctions are known as bound states, in contrast to the class (ii) solutions that are known as scattering states.

For negative W the quantity Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \alpha \equiv 2\sqrt{-2W}} is real and positive. The scaling of y, i.e., substitution of Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle x \equiv \alpha y } gives the Schrödinger equation:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left[ \frac{d^2}{dx^2} -\frac{l(l+1)}{x^2}+\frac{2}{\alpha x} - \frac{1}{4} \right] u_l = 0, \quad \hbox{with}\quad x \ge 0. }

For Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle x \rightarrow \infty} the inverse powers of x are negligible and a solution for large x is Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \exp[-x/2]} . The other solution, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \exp[x/2]} , is physically non-acceptable. For Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle x \rightarrow 0} the inverse square power dominates and a solution for small x is x^l+1. The other solution, x^-l, is physically non-acceptable. Hence, to obtain a full range solution we substitute

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle u_l(x) = x^{l+1} e^{-x/2}f_l(x).\, }

The equation for f_l(x) becomes,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left[ x\frac{d^2}{dx^2} + (2l+2-x) \frac{d}{dx} +(\nu -l-1)\right] f_l(x) = 0 \quad\hbox{with}\quad \nu = (-2W)^{-\frac{1}{2}}. }

Provided Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \nu-l-1} is a non-negative integer, say k, this equation has polynomial solutions written as

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle L^{(2l+1)}_{k}(x),\qquad k=0,1,\ldots , }

which are generalized Laguerre polynomials of order k. We will take the convention for generalized Laguerre polynomials of Abramowitz and Stegun. Note that the Laguerre polynomials given in many quantum mechanical textbooks, for instance the book of Messiah, are those of Abramowitz and Stegun multiplied by a factor (2l+1+k)! The definition given in this article coincides with the one of Abramowitz and Stegun.

The energy becomes

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle W = -\frac{1}{2n^2}\quad \hbox{with}\quad n \equiv k+l+1 . }

The principal quantum number n satisfies Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle n \ge l+1} , or Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle l \le n-1} . Since Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \alpha = 2/n} , the total radial wavefunction is

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle R_{nl}(r) = N_{nl} \left(\tfrac{2Zr}{na_0}\right)^{l}\; e^{-{\textstyle \frac{Zr}{na_0}}}\; L^{(2l+1)}_{n-l-1}\left(\tfrac{2Zr}{na_0}\right), }

with normalization constant

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle N_{nl} = \left[\left(\frac{2Z}{na_0}\right)^3 \cdot \frac{(n-l-1)!}{2n[(n+l)!]}\right]^{1 \over 2}}

which belongs to the energy

$E_{n}=-{\frac {Z^{2}}{2n^{2}}}E_{\textrm {h}},\qquad n=1,2,\ldots .$

In the computation of the normalization constant use was made of the integral

$\int _{0}^{\infty }x^{2l+2}e^{-x}\left[L_{n-l-1}^{(2l+1)}(x)\right]^{2}dx={\frac {2n(n+l)!}{(n-l-1)!}}.$