User:Milton Beychok/Sandbox

Liquefied natural gas or LNG is natural gas (predominantly methane, CH₄) that has been converted into liquid form for ease of transport and storage. More simply put, it is the liquid form of the natural gas that people use in their homes for cooking and for heating,

A typical raw natural gas contains only about 80% methane and a number of higher boiling hydrocarbons as well as a number of impurities. Before it is liquefied, it is typically purified so as to remove the higher-boiling hydrocarbons and the impurities. The resultant liquefied natural gas contains about 95% or more methane and it is a clear, colorless and essentially odorless liquid which is neither corrosive nor toxic.

LNG occupies only a very small fraction (1/600th) of the volume of natural gas and is therefore more economical to transport across large distances. It can also be stored in large quantities that would be impractical for storage as a gas.

Process description for the production of LNG

(CC) Diagram: Milton Beychok
Fig.1: Block flow diagram of the LNG liquefaction process. See Natural gas processing for more details.

The liquefaction process involves separating the raw natural gas from any associated water and high-boiling hydrocarbon liquids (referred to as natural gas condensate) that may be associated with the raw gas. The raw gas is then further purified in a natural gas processing plant to remove remove impurities such as the acid gases hydrogen sulfide (H₂S) and carbon dioxide (CO₂), any residual water liquid or vapor, mercury, nitrogen and helium which could cause difficulty downstream. ( See the block flow diagram of the liquefaction process in Fig.1)

The purified natural gas is next refrigerated and distilled to recover ethane (C₂H₆), propane (C₃H₈), butanes (C₄H₁₀) and any higher boiling hydrocarbons, collectively referred to as natural gas liquids (NGL). The natural gas is then condensed into a liquid at essentially atmospheric pressure by using further refrigeration to cool it to approximately -162 °C (260 °F).

As mentioned above, the reduction in volume makes LNG much more cost efficient to transport over long distances where pipelines do not exist. Where transporting natural gas by pipelines is not possible or economical, it can be transported by specially designed cryogenic sea vessels called LNG carriers or by either cryogenic rail or road tankers.

History

Natural gas liquefaction dates back to the 1820s when British physicist Michael Faraday experimented with liquefying different types of gases. German engineer Carl Von Linde built the first practical vapor-compression refrigeration system in the 1870s.

The first commercial LNG liquefaction plant was built in Cleveland, Ohio, in 1941 and the LNG was stored in tanks at atmospheric pressure, which raised the possibility that LNG could be transported in sea-going vessels. In January 1959, the world's first LNG carrier, a converted freighter named The Methane Pioneer, containing five small, insulated aluminum tanks transported 5,000 m³ of LNG from Lake Charles, Louisiana in the United States to Canvey Island in England's Thames river. That voyage demonstrated that LNG could be transported safely across the oceans. During the next 14 months, that same freighter delivered seven additional cargoes with only a few small problems.

LNG transportation

(CC) Photo: Xoán Porto
LNG tanker with 5 spherical LNG tanks. Total length is 285 metres (311 yards).

LNG Terminals

(PD) Photo: Yo-sei Shosi
LNG storage tanks in LNG terminal at Yokohama, Japan.