User:Milton Beychok/Sandbox

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(CC) Photo: Luigi Chiesa
Industrial continuous distillation columns.

Continuous distillation is an ongoing process in which a liquid mixture of two or more miscible components is continuously fed into the process and continuously separated into two or more products by preferentially boiling the more volatile components out of the mixture. [1][2][3][4]

Large-scale, continuous distillation is used widely in the chemical process industries where large quantities of liquids have to be distilled, as in petroleum refining, natural gas processing, petrochemical production, coal tar processing and the liquefaction of gases such as hydrogen, oxygen, nitrogen, and helium).

Industrial distillation is typically performed in large, vertical cylindrical columns (see adjacent photograph) known as "distillation towers" or "distillation columns" with diameters ranging from about 65 centimeters to 11 meters and heights ranging from about 6 meters to 60 meters or more.

Distillation is one of the important unit operations of chemical engineering. If the feed contains more than two components, it is referred to as multi-component distillation and, if it contains only two components, it is referred to as binary distillation.

Principle

When a liquid mixture is heated, the evolved vapor will have a higher concentration of the more volatile (i.e., lower boiling point) components than the liquid from which it evolved. Conversely, if a vapor mixture is cooled, the less volatile components will tend to condense in a higher proportion than the more volatile components.

  1. Kister, Henry Z. (1992). Distillation Design, 1st Edition. McGraw-Hill. ISBN 0-07-034909-6. 
  2. King, C.J. (1980). Separation Processes. McGraw Hill. 0-07-034612-7. 
  3. Perry, Robert H. and Green, Don W. (2007). Perry's Chemical Engineers' Handbook, 8th Edition. McGraw-Hill. ISBN 0-07-142294-3. 
  4. McCabe, W., Smith, J. and Harriott, P. (2004). Unit Operations of Chemical Engineering, 7th Edition. McGraw Hill. ISBN 0-07-284823-5.