User talk:Paul Wormer/scratchbook1: Difference between revisions

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The '''Jahn-Teller effect''' is the distortion of a highly symmetric—but non-linear—molecule to lower symmetry and lower  energy. The effect occurs if the molecule is in a degenerate state of definite energy, that is, more than one wave function is eigenstate  with the same energy of  the [[molecular Hamiltonian]]. In other words, energy degeneracy of a state implies that two or more orthogonal wave functions describe the  state. Due to  Jahn-Teller distortion, the molecule is lowered in symmetry and the energy degeneracy is lifted. One or more wave functions become non-degenerate eigenstates of lower energies, while others wave function  rise in energy.
==Parabolic mirror==
{{Image|Refl parab.png|right|350px|Fig. 2. Reflection in a parabolic mirror}}
Parabolic mirrors concentrate incoming vertical light beams in their focus. We show this.


The effect is named after [[Hermann Jahn|H. A. Jahn]] and [[Edward Teller|E. Teller]] who predicted it in 1937<ref>H. A. Jahn and E. Teller, ''Stability of Polyatomic Molecules in Degenerate Electronic States'', Proc. Royal Soc. vol. '''161''', pp. 220&ndash;235 (1937)</ref>. It took some time before the effect was experimentally observed, because it was masked by other molecular interactions. However, there are now numerous unambiguous observations that agree well with theoretical predictions. These range from the excited states of the simplest non-linear molecule H<sub>3</sub> through moderate sized organic molecules, like ions of substituted [[benzene]], to complex [[crystal]]s and localized impurity centers in solids.
Consider in figure  2 the arbitrary  vertical light beam (blue, parallel to the ''y''-axis) that enters the parabola and hits it at point ''P'' = (''x''<sub>1</sub>, ''y''<sub>1</sub>). The parabola (red) has focus in point ''F''. The incoming beam is reflected at ''P'' obeying the well-known law:  incidence angle is angle of reflection.  The angles involved are with the line  ''APT'' which is tangent to the parabola at point ''P''. It will be shown that the reflected beam passes through ''F''.  


<font style = "font-size: 80%; font-style: oblique; font-weight: bolder" >
Clearly &ang;''BPT'' = &ang;''QPA'' (they are vertically opposite angles). Further &ang;''APQ'' = &ang;''FPA'' because the triangles ''FPA'' and ''QPA'' are congruent and hence  &ang;''FPA'' = &ang;''BPT''.
The Jahn-Teller effect is based on a quantum mechanical mechanism and no classical description of it existsFrom here on some knowledge of quantum mechanics is prerequisite to the reading of this article.</font>
 
We prove the congruence of the triangles: By the definition of  the parabola the line segments ''FP'' and ''QP'' are of equal length, because the length of the latter segment is the distance of ''P'' to the directrix and the length of ''FP'' is the distance of ''P'' to the focus.  The point ''F'' has the coordinates (0,''f'') and the point ''Q'' has the coordinates (''x''<sub>1</sub>, &minus;''f''). The line segment ''FQ'' has the equation
:<math>
\lambda\begin{pmatrix}0\\ f\end{pmatrix} + (1-\lambda)\begin{pmatrix}x_1\\ -f\end{pmatrix}, \quad 0\le\lambda\le 1.
</math>
The midpoint ''A''  of ''FQ'' has coordinates (&lambda; = &frac12;):
:<math>
\frac{1}{2}\begin{pmatrix}0\\ f\end{pmatrix} + \frac{1}{2}\begin{pmatrix}x_1\\ -f\end{pmatrix} =
\begin{pmatrix}\frac{1}{2} x_1\\ 0\end{pmatrix}.
</math>
Hence ''A'' lies on the ''x''-axis.
The parabola has equation,
:<math>
y = \frac{1}{4f} x^2.
</math>
The equation of the tangent at ''P'' is
:<math>
y = y_1 + \frac{x_1}{2f} (x-x_1)\quad \hbox{with}\quad y_1 = \frac{x_1^2}{4f}.
</math>
This line intersects the ''x''-axis at ''y'' = 0,
:<math>
0 = \frac{x_1^2}{4f} - \frac{x_1^2}{2f} + \frac{x_1}{2f} x
\Longrightarrow \frac{x_1}{2f} x = \frac{x_1^2}{4f} \longrightarrow x = \tfrac{1}{2}x_1.
</math>
The intersection of the tangent with the ''x''-axis is the point ''A'' = (&frac12;''x''<sub>1</sub>, 0) that lies on the midpoint of ''FQ''. The corresponding sides of the triangles ''FPA'' and ''QPA'' are of equal length and hence the triangles are congruent.

Latest revision as of 00:40, 4 April 2010

Parabolic mirror

PD Image
Fig. 2. Reflection in a parabolic mirror

Parabolic mirrors concentrate incoming vertical light beams in their focus. We show this.

Consider in figure 2 the arbitrary vertical light beam (blue, parallel to the y-axis) that enters the parabola and hits it at point P = (x1, y1). The parabola (red) has focus in point F. The incoming beam is reflected at P obeying the well-known law: incidence angle is angle of reflection. The angles involved are with the line APT which is tangent to the parabola at point P. It will be shown that the reflected beam passes through F.

Clearly ∠BPT = ∠QPA (they are vertically opposite angles). Further ∠APQ = ∠FPA because the triangles FPA and QPA are congruent and hence ∠FPA = ∠BPT.

We prove the congruence of the triangles: By the definition of the parabola the line segments FP and QP are of equal length, because the length of the latter segment is the distance of P to the directrix and the length of FP is the distance of P to the focus. The point F has the coordinates (0,f) and the point Q has the coordinates (x1, −f). The line segment FQ has the equation

The midpoint A of FQ has coordinates (λ = ½):

Hence A lies on the x-axis. The parabola has equation,

The equation of the tangent at P is

This line intersects the x-axis at y = 0,

The intersection of the tangent with the x-axis is the point A = (½x1, 0) that lies on the midpoint of FQ. The corresponding sides of the triangles FPA and QPA are of equal length and hence the triangles are congruent.